Dess-Martin (DMP), a hypervalent iodine compound, provides a actual bendable and careful blaze of alcohols to aldehydes or ketones.1 ° and 2 ° alcohols to aldehydes and ketones oxidant oxidized. tetraone for the blaze of chloro and hydroxy dione chlorine.
It is based on IBX, but because of the acetate groups to the axial atom iodine, DMP is abundant added acknowledging than IBX and is added acrid in amoebic solvents.
This periodinane has several advantages over Chromium oxidants and DMSO-based, the milder altitude (room temperature, pH-neutral), simplified chain are college yields, beneath acknowledgment times, and top chemo-, altruism acute anatomic groups and a continued account life.
more about: Dess-Martin Periodinane
from: Pharmaceutical Ingredients
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